(R,R)DIPAMP-RUTHENIUM(II) (2-METHYLALLYL)2 - SYNTHESIS AND SELECTED USE IN ASYMMETRIC HYDROGENATION

被引：38

作者：

GENET, JP

PINEL, C

MALLART, S

JUGE, S

CAILHOL, N

LAFFITTE, JA

机构：

[1] Laboratoire de Synthese Organique. Associe au C.N.R.S. Ecole Nationale Superieure de Chimie de Paris, 75231 Paris

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 37期

关键词：

ASYMMETRIC HYDROGENATION; CATALYSIS; CHIRAL RUTHENIUM COMPLEXES; DIPAMP;

D O I：

10.1016/S0040-4039(00)79088-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of (R, R)DIPAMP ruthenium bis (2-methylallyl) 2 and halogeno derivative (R, R) DIPAMPRu2X2 3 complexes is presented, which uses the easily available from (COD)2Ru(2-methylallyl)2. 1. These new catalysts were found to be effective for asymmetric hydrogenation of both olefins and keto groups (35-80% ee).

引用

页码：5343 / 5346

页数：4

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