INTEGRAL RATE-CONSTANT MEASUREMENTS OF THE REACTION H+D2-]HD(UPSILON'=1,J')+D AT HIGH COLLISION ENERGIES

被引：22

作者：

ADELMAN, DE

XU, H

ZARE, RN

机构：

[1] Department of Chemistry, Stanford University, Stanford

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 203卷 / 5-6期

基金：

加拿大自然科学与工程研究理事会; 美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(93)85312-C

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction H + D2 --> HD(nu' = 1,j')+D was studied using two different experimental geometries: (1) a probe-laser-induced reaction geometry and (2) an independent-photolysis laser geometry. High-energy H atoms were generated by photolysis of HI which resulted in center-of-mass collision energies of 2.2 and 2.5 eV for geometries 1 and 2, respectively. The HD product was detected using (2 + 1) REMPI and time-of-flight mass spectrometry. The HD (nu' = 1, j') rotational distributions are presented; at this time no corresponding theoretical calculations are available for comparison.

引用

收藏

页码：573 / 577

页数：5

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