THE STEREOCHEMISTRY OF ENAMIDE INTERMEDIATES IN DUPHOS-RH(I) CATALYZED ASYMMETRIC HYDROGENATION

被引：52

作者：

ARMSTRONG, SK ^{[1
]}

BROWN, JM ^{[1
]}

BURK, MJ ^{[1
]}

机构：

[1] DUPONT CO,CENT RES & DEV LABS,EXPTL STN,WILMINGTON,DE 19880

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 05期

关键词：

D O I：

10.1016/0040-4039(93)89038-R

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stereochemical aspects of the title reaction were investigated for the (S,S)-Me-DuPHOS ligand 5a, largely by NMR examination of Ir complexes They were found to behave in an analogous fashion to that established for P-aryl diphosphine-rhodium(I) complexes.

引用

页码：879 / 882

页数：4

共 12 条

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