NITRO ALKANES IN ORGANIC-SYNTHESIS - AN EFFICIENT STEREOSELECTIVE SYNTHESIS OF (+)-TRANS-WHISKEY LACTONE AND (+)-ELDANOLIDE FROM NITRO ALKANE SYNTHONS AND USING BAKERS-YEAST REDUCTION AS THE KEY STEP

被引：37

作者：

SARMAH, BK ^{[1
]}

BARUA, NC ^{[1
]}

机构：

[1] CSIR,DIV NAT PROD CHEM,REG RES LAB,JORHAT 785006,INDIA

来源：

TETRAHEDRON | 1993年 / 49卷 / 11期

关键词：

D O I：

10.1016/S0040-4020(01)80369-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient route using nitroalkane synthon 3a and 3b for the synthesis of optically pure R-(+)-trans whisky lactone, (+)-9 and R-(+)-eldanolide, (+)-10 is described. In a key step, bakers' yeast reduction is employed to get the required chirality.

引用

页码：2253 / 2260

页数：8

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