STRUCTURAL INVESTIGATION INTO THE SURPRISING STABILITY OF FREE AND COMPLEXED BIS(AMINO)PHOSPHINE AZIDES

被引：10

作者：

COWLEY, AH

GABBAI, FP

BERTRAND, G

CARRANO, CJ

BOND, MR

机构：

[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712

[2] CNRS,CHIM COORDINAT LAB,F-31077 TOULOUSE,FRANCE

[3] SW TEXAS STATE UNIV,DEPT CHEM,SAN MARCOS,TX 78666

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 493卷 / 1-2期

关键词：

BIS(AMINO)PHOSPHINE AZIDE COMPLEXES; REACTIVITY; X-RAY STRUCTURE;

D O I：

10.1016/0022-328X(95)91149-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of ((Pr2N)-Pr-i)(2)PN3 (1) with Fe-2(CO)(9) in toluene solution at 25 degrees C produces the complex ((Pr2N)-Pr-i)(2)P(N-3)-Fe(CO)(4) (3) with a high yield. The cophotolysis of 1 and Cr(CO)(6) in tetrahydrofuran solution results in the formation of ((Pr2N)-Pr-i)(2)P(N-3)-Cr(CO)(5) (4). Complexes 3 and 4 were found to be stable to UV irradiation (254 nm). The chromium complex 4 and the free phosphine azide (c-Hex(2)N)(2)PN3 (2) have been characterized by single-crystal X-ray diffraction.

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页码：95 / 99

页数：5

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