THE SELF-ASSEMBLY OF CATENATED CYCLODEXTRINS

被引：85

作者：

ARMSPACH, D

ASHTON, P

MOORE, CP

SPENCER, N

STODDART, JF

WEAR, TJ

WILLIAMS, DJ

机构：

[1] UNIV BIRMINGHAM, SCH MED, BIRMINGHAM B15 2TT, W MIDLANDS, ENGLAND

[2] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED, DEPT CHEM, CHEM CRYSTALLOG LAB, LONDON SW7 2AZ, ENGLAND

[3] KODAK LTD, HARROW HA1 4TY, MIDDX, ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1993年 / 32卷 / 06期

关键词：

D O I：

10.1002/anie.199308541

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Schotten-Baumann reaction between a diamine with a central bitolyl unit and terephthaloyl chloride in the presence of heptakis(2,6-di-0-methyl)-beta-cyclodextrin (Dm-beta-CD) in dilute solution affords the [2]catenanes 1 and 2 as well as two analogous [3]catenanes, in which two DM-beta-CD units are threaded on a tetrakislactam ring. In catenane 1 the bitolyl unit is found to be situated inside the cyclodextrin torus.

引用

页码：854 / 858

页数：5

共 47 条

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