SINGLE-ELECTRON TRANSFER IN THE REACTION OF AN ALKYL IODIDE WITH LIALH(4) AND LIALD(4) IN THE ABSENCE OF A HALOGEN ATOM RADICAL-CHAIN PROCESS

被引：11

作者：

ASHBY, EC

WELDER, CO

DOCTOROVICH, F

机构：

[1] School of Chemistry and Biochemistry, Georgia Institute of Technology Atlanta

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 45期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)79296-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions of the noncyclizable alkyl iodide, 1-iodo-2,2-dimethylhexane (9), with LiAlH4 and LiAlD4 have been carried out under a variety of conditions. Although the structure of 9 prohibits a halogen atom radical chain process, deuterium incorporation studies provide convincing evidence for single electron transfer (SET) as the major reaction pathway.

引用

页码：7235 / 7238

页数：4

共 5 条

[1] SINGLE-ELECTRON TRANSFER, A MAJOR REACTION PATHWAY IN ORGANIC-CHEMISTRY - AN ANSWER TO RECENT CRITICISMS [J].