MOLECULAR RECOGNITION OF ANIONS BY ZWITTERIONIC HOST MOLECULES IN WATER

被引：67

作者：

WORM, K

SCHMIDTCHEN, FP

机构：

[1] Institut für Organische Chemie, Biochemie der Technische Universität München, Garching, D-85747

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 01期

关键词：

ANION COMPLEXATION; HOST-GUEST CHEMISTRY; MOLECULAR RECOGNITION;

D O I：

10.1002/anie.199500651

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Up to now cationic hosts were necessary for the molecular recognition of hydrophilic anions in water. This task can, however, also be performed with the cage molecule 1 having zero net charge. The vital design feature is the rigid separation of substructures of unlike charge, which enables encapsulation of the guest in the central cavity. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

收藏

页码：65 / 66

页数：2

相关论文

共 21 条

[1] 1,8-DIMETHYL-1,8-DIHALO-1,8-DIGERMACYCLOTETRADECANES - THE 1ST GERMAMACROCYCLES WITH ANION TRANSPORT CAPABILITY [J].

AOYAGI, S ;

TANAKA, K ;

TAKEUCHI, Y .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1994, (07) :1549-1553

[2] THERMODYNAMIC STUDY ON THE EFFECTS OF BETA-CYCLODEXTRIN INCLUSION WITH ANILINONAPHTHALENESULFONATES [J].

CATENA, GC ;

BRIGHT, FV .

ANALYTICAL CHEMISTRY, 1989, 61 (08) :905-909

[3] A NEW WATER-SOLUBLE MACROCYCLIC HOST OF THE CYCLOPHANE TYPE - HOST GUEST COMPLEXATION WITH AROMATIC GUESTS IN AQUEOUS-SOLUTION AND ACCELERATION OF THE TRANSPORT OF ARENES THROUGH AN AQUEOUS PHASE [J].

DIEDERICH, F ;

DICK, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (26) :8024-8036

[4] DESIGN OF ANION RECEPTORS - APPLICATIONS [J].

DIETRICH, B .

PURE AND APPLIED CHEMISTRY, 1993, 65 (07) :1457-1464

[5] HOST-GUEST CHEMISTRY OF ANION-COMPLEXATION BY MACROCYCLIC MULTIDENTATE LEWIS-ACIDS [J].

HAWTHORNE, MF ;

YANG, XG ;

ZHENG, ZP .

PURE AND APPLIED CHEMISTRY, 1994, 66 (02) :245-254

[6] CHLORIDE BINDING BY POLYAMMONIUM RECEPTOR MOLECULES - CL-35-NMR STUDIES [J].

HOSSEINI, MW ;

KINTZINGER, JP ;

LEHN, JM ;

ZAHIDI, A .

HELVETICA CHIMICA ACTA, 1989, 72 (05) :1078-1083

[7] ANORMALY OF CL-35 NMR SPIN-LATTICE RELAXATION RATE FOR THE CHLORIDE ANION IN THE CAPSULAR COMPLEX WITH MACROTRICYCLIC QUATERNARY AMMONIUM ION [J].

ICHIKAWA, K ;

YAMAMOTO, A ;

HOSSAIN, MA .

CHEMISTRY LETTERS, 1993, (12) :2175-2178

[8] THERMODYNAMICS OF MOLECULAR RECOGNITION BY CYCLODEXTRINS .1. CALORIMETRIC TITRATION OF INCLUSION COMPLEXATION OF NAPHTHALENESULFONATES WITH ALPHA-CYCLODEXTRIN, BETA-CYCLODEXTRIN, AND GAMMA-CYCLODEXTRIN - ENTHALPY ENTROPY COMPENSATION [J].

INOUE, Y ;

HAKUSHI, T ;

LIU, Y ;

TONG, LH ;

SHEN, BJ ;

JIN, DS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (02) :475-481

[9] MULTIDENTATE LEWIS-ACIDS - THEORETICAL-STUDY OF ANION-BINDING BY ORGANOBORON MACROCYCLIC HOSTS [J].

JACOBSON, S ;

PIZER, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (24) :11216-11221

[10] 1,8-ANTHRACENEDIETHYNYLBIS(CATECHOL BORONATE) - A BIDENTATE LEWIS ACID ON A NOVEL FRAMEWORK [J].

KATZ, HE .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (09) :2179-2183