SYNTHESIS AND PROPERTIES OF 1,2-DIFLUORODINITROETHYLENE

被引：20

作者：

BAUM, K ^{[1
]}

ARCHIBALD, TG ^{[1
]}

TZENG, D ^{[1
]}

GILARDI, R ^{[1
]}

FLIPPENANDERSON, JL ^{[1
]}

GEORGE, C ^{[1
]}

机构：

[1] USN,RES LAB,STRUCT MATTER LAB,WASHINGTON,DC 20375

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 02期

关键词：

D O I：

10.1021/jo00002a011

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,2-Difluorodinitroethylene was synthesized by flash vacuum pyrolysis of 1,2-difluorotetranitroethane. X-ray crystallography showed that one of the two nitro groups is out of the plane of the rest of the molecule and that the C-C double-bond distance is unusually short at 1.284 angstrom. 1,2-Difluorotetranitroethane reacted with alcohols to give alkyl fluoronitroacetates and with anthracene and cyclopentadiene to give Diels-Alder adducts.

引用

页码：537 / 539

页数：3

共 10 条

[1]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[2] SYNTHESIS AND REACTIONS OF TETRANITROETHYLENE [J].