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BULK THERMAL COPOLYMERIZATION OF STYRENE P-METHYLSTYRENE - MODELING DIFFUSION-CONTROLLED TERMINATION AND PROPAGATION USING FREE-VOLUME THEORY

被引：30
作者：
BHATTACHARYA, D
HAMIELEC, AE
机构：
[1] McMaster Univ, Hamilton, Ont, Can, McMaster Univ, Hamilton, Ont, Can
来源：
POLYMER | 1986年 / 27卷 / 04期
基金：
加拿大自然科学与工程研究理事会;
关键词：
CHEMICAL REACTIONS - Reaction Kinetics - DIFFUSION - MATHEMATICAL MODELS - POLYMERIZATION - Copolymerization - STYRENE;
D O I：
10.1016/0032-3861(86)90248-X
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The development of a kinetic model for the bulk thermal copolymerization of styrene/p-methylstyrene (PMS) is reported. Free-volume theory has been used to model diffusion controlled termination and propagation. This kinetic model is in reasonable agreement with published rate and molecular weight data on thermal homopolymerization of styrene and PMS as well as with data for the copolymerization of these monomers.
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页码：611 / 618
页数：8
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