DIHALO DERIVATIVES OF 3-COORDINATE HYPERVALENT PHOSPHORUS-COMPOUNDS

被引：11

作者：

ARDUENGO, AJ

BREKER, J

DAVIDSON, F

KLINE, M

机构：

[1] Du Pont Central Research, Experimental Station, Wilmington, Delaware

来源：

HETEROATOM CHEMISTRY | 1993年 / 4卷 / 2-3期

关键词：

D O I：

10.1002/hc.520040215

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation of 1,1-difluoro-3,7-di-tert-butyl-2,8-dioxa-1-phosphabicyclo[3.3.0]octa-3,6-diene (Dit-BuADPO . F2) from hexafluoropropylene oxide (HFPO) and 3,7-di-tert-butyl-2,8-dioxa-1-phosphabicyclo-[3.3.0]octa-2,4,6-triene (DitBuADPO) is described. The solid state structure of DitBuADPO . F2 shows an unusual square pyramidal geometry. The structural and spectroscopic properties of DitBuADPO . F2 are compared with other oxidized derivatives of DitBuADPO that contain 5-coordinate phosphorus.

引用

页码：213 / 221

页数：9

共 16 条

[1]

Arduengo A. J., 1990, HETEROATOM CHEM, V1, P407

[2]

Arduengo A. J., 1991, HETEROATOM CHEM, V2, P395

[3] PENTACOORDINATE 10-ELECTRON PNICTOGEN MANGANESE ADDUCTS - VERIFICATION OF THE 10-PN-3 ARRANGEMENT IN ADPNO MOLECULES [J].