A TUNGSTEN CARBONYL COMPLEX [W(CO) (PH2PCH2CH2PPH2)2] PRESENT AS A MIXTURE OF 2 SPECIES HAVING AGOSTIC INTERACTION OR ORTHO-METALLATION AND ITS REACTION WITH HYDROGEN GAS

被引：8

作者：

ISHIDA, T ^{[1
]}

MIZOBE, Y ^{[1
]}

HIDAI, M ^{[1
]}

机构：

[1] UNIV TOKYO, FAC ENGN, DEPT SYNTHET CHEM, BUNKYO KU, TOKYO 113, JAPAN

来源：

CHEMISTRY LETTERS | 1989年 / 11期

关键词：

D O I：

10.1246/cl.1989.2077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：2077 / 2080

页数：4

共 11 条

[1] CARBON-HYDROGEN-TRANSITION METAL BONDS [J].

BROOKHART, M ;

GREEN, MLH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 250 (01) :395-408

[2] SOME MOLECULAR-HYDROGEN COMPLEXES OF IRIDIUM [J].

CRABTREE, RH ;

LAVIN, M ;

BONNEVIOT, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (14) :4032-4037

[3] H-H, C-H, AND RELATED SIGMA-BONDED GROUPS AS LIGANDS [J].

CRABTREE, RH ;

HAMILTON, DG .

ADVANCES IN ORGANOMETALLIC CHEMISTRY, 1988, 28 :299-338

[4] PREPARATION AND PROPERTIES OF MOLYBDENUM AND TUNGSTEN DINITROGEN COMPLEXES .24. DECARBONYLATION REACTION OF DIMETHYLFORMAMIDE (DMF) WITH TRANS-[W(N2)2(PH2PCH2CH2PPH2)2] - PREPARATION AND CHARACTERIZATION OF [WH(ETA-2-CONME2)(PH2PCH2CH2PPH2)2] AND [W(CO)(DMF)(PH2PCH2CH2PPH2)2] [J].

ISHIDA, T ;

MIZOBE, Y ;

TANASE, T ;

HIDAI, M .

CHEMISTRY LETTERS, 1988, (03) :441-444

[5] INTERACTION BETWEEN D6 ML5 METAL FRAGMENTS AND HYDROGEN - ETA-2-H-2 VS DIHYDRIDE STRUCTURE [J].

JEAN, Y ;

EISENSTEIN, O ;

VOLATRON, F ;

MAOUCHE, B ;

SEFTA, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (21) :6587-6592

[6] SYNTHESES AND SOME REACTIONS OF TRIMETHYLSILYLATED DINITROGEN COMPLEXES OF TUNGSTEN AND MOLYBDENUM [J].

KOMORI, K ;

SUGIURA, S ;

MIZOBE, Y ;

YAMADA, M ;

HIDAI, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1989, 62 (09) :2953-2959

[7] MOLECULAR-HYDROGEN COMPLEXES OF THE TRANSITION-METALS .2. EVIDENCE FOR A NEW COMPLEX, MO(CO)(DPPE)2(H2), AND FOR SOLUTION EQUILIBRIUM BETWEEN DIHYDROGEN AND DIHYDRIDE FORMS, M-ETA-2-H2 REVERSIBLE H-M-H, IN W(CO)3(PR3)2(H2) [J].

KUBAS, GJ ;

RYAN, RR ;

WROBLESKI, DA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (06) :1339-1341

[8] MOLECULAR-HYDROGEN COMPLEXES .5. ELECTRONIC CONTROL OF ETA2-H2 VERSUS DIHYDRIDE COORDINATION - DIHYDRIDE STRUCTURE OF MOH2(CO)(R2PC2H4PR2)2 FOR R = ET, I-BU VERSUS ETA2-H2 FOR R = PH [J].

KUBAS, GJ ;

RYAN, RR ;

UNKEFER, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (26) :8113-8115

[9] DIHYDROGEN VS DIHYDRIDE - CORRELATIONS BETWEEN ELECTROCHEMICAL OR UV PES DATA AND FORCE-CONSTANTS FOR CARBONYL OR DINITROGEN LIGANDS IN OCTAHEDRAL, D6 COMPLEXES AND THEIR USE IN EXPLAINING THE BEHAVIOR OF THE DIHYDROGEN LIGAND [J].

MORRIS, RH ;

EARL, KA ;

LUCK, RL ;

LAZAROWYCH, NJ ;

SELLA, A .

INORGANIC CHEMISTRY, 1987, 26 (16) :2674-2683

[10] PREPARATION AND PROPERTIES OF DINITROGEN-MOLYBDENUM COMPLEXES .6. SYNTHESES AND MOLECULAR-STRUCTURES OF A 5-COORDINATE MO(O) COMPLEX MO(CO)(PH2PCH2CH2PPH2)2AND A RELATED 6-COORDINATE COMPLEX "MO(CO)(N2)(PH2PCH2CH2PPH2)2-1/2C6H6 [J].

SATO, M ;

TATSUMI, T ;

KODAMA, T ;

HIDAI, M ;

UCHIDA, T ;

UCHIDA, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (14) :4447-4452

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