UNSATURATION IN A HIGH-NUCLEARITY METAL-CARBONYL CLUSTER COMPLEX - SYNTHESIS, STRUCTURES, AND INTERCONVERSIONS OF PT2OS4(CO)12(COD)2 AND PT2OS4(CO)11(COD)2

被引：10

作者：

ADAMS, RD

WU, WG

机构：

[1] Department of Chemistry, University of South Carolina, Columbia

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 01期

关键词：

D O I：

10.1021/om00047a019

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The two new platinum-osmium carbonyl cluster complexes Pt2Os4(CO)12(COD)2 (1) and Pt2Os4(CO)11(COD)2 (2) were obtained from the reaction of Pt2Os4(CO)18 with 1,5-cyclooctadiene (COD) at 97-degrees-C. Both compounds consist of a bicapped Os4 tetrahedron. Compound 1 is coordinatively saturated, while compound 2 is coordinatively unsaturated. The latter contains several unusually short metal-metal bonds and readily adds CO to give 1 in good yield.

引用

页码：35 / 36

页数：2

共 13 条

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