SOME CHIRAL ALKYNE-COBALT COMPLEXES

被引：18

作者：

DUNN, JA ^{[1
]}

PAUSON, PL ^{[1
]}

机构：

[1] UNIV STRATHCLYDE,DEPT PURE & APPL CHEM,CATHEDRAL ST,GLASGOW G1 1XL,SCOTLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 419卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)80250-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The trimethyl phosphite substituted pentacarbonylpropargyldicobalt cation, [(CH = CCH2) Co2(CO)5L]+ [L = P(OMe)3], is significantly more stable than its phosphine analogues (L = PPh3, PBu3), and has been converted to a series of ethers, (CH = CCH2OR)Co2(CO)5L. Reaction of the (cholesteryl propargyl ether)hexacarbonyldicobalt complex with trimethyl phosphite proceeds without stereoselectivity, and the product suffers metal-carbon rather than oxygen-carbon cleavage on treatment with acid.

引用

页码：383 / 389

页数：7

共 9 条

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