CATALYST-SUBSTRATE COMPLEXES OF CHIRAL 7-MEMBERED RING CHELATES OF RHODIUM(I)-BIS(PHOSPHINITES)

被引：29

作者：

KADYROV, R

FREIER, T

HELLER, D

MICHALIK, M

SELKE, R

机构：

[1] UNIV ROSTOCK,MAX PLANCK GESELL,ARBEITSGRP ASYMMETR KATALYSE,D-18055 ROSTOCK,GERMANY

[2] UNIV ROSTOCK EV,INST ORGAN KATALYSEFORSCH,ROSTOCK,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 17期

关键词：

D O I：

10.1039/c39950001745

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Line-shape analysis of P-31 NMR spectra of catalyst substrate complexes of seven-membered ring rhodium(I)bisphosphinites indicate for the first time a quantifiable preference of the intramolecular major-minor isomerisation of both diastereoisomeric chelates of dimethyl itaconate over the slow intermolecular interconversion.

引用

页码：1745 / 1746

页数：2

共 16 条

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