ORTHORHOMBIC DIMAGNESIUM RUTHENIUM TETRAHYDRIDE CONTAINING A DIAMAGNETIC [RUH4]4- COMPLEX ANION WITH C2V SYMMETRY

被引：26

作者：

BONHOMME, F

YVON, K

TRISCONE, G

JANSEN, K

AUFFERMANN, G

MULLER, P

BRONGER, W

FISCHER, P

机构：

[1] UNIV GENEVA,DEPT PHYS MAT CONDENSEE,CH-1211 GENEVA,SWITZERLAND

[2] RHEIN WESTFAL TH AACHEN,INST ANORGAN CHEM,W-5100 AACHEN,GERMANY

[3] ERDGENOSS TH ZURICH,NEUTRONENSTREUUNG LAB,CH-5232 VILLIGEN,SWITZERLAND

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1992年 / 178卷

关键词：

D O I：

10.1016/0925-8388(92)90257-A

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dimagnesium ruthenium tetrahydride (Mg2RuH4) and its deuteride were synthesized by the reaction of magnesium with ruthenium under a hydrogen (deuterium) pressure and characterized by X-ray and neutron powder diffraction. The compound crystallizes in the orthorhombic space group Cmcm. The structure contains a new 16-electron low spin [RuD4]4- complex anion of C2v symmetry which derives from the octahedral 18-electron [RuD6]4- complex anion in Mg2RuD6 by removal of two cis deuterium ligands.

引用

页码：161 / 166

页数：6

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