MICROSTRUCTURE EVOLUTION DURING REACTIVE PLASMA SPRAYING OF MOSI2 WITH METHANE

被引:13
作者
LIANG, X
LAVERNIA, EJ
WOLFENSTINE, J
SICKINGER, A
机构
[1] UNIV CALIF IRVINE,IRVINE,CA 92717
[2] SULZER METCO IRVINE INC,IRVINE,CA 92714
关键词
MOSI2; MICROSTRUCTURE EVOLUTION; REACTIVE PLASMA SPRAYING;
D O I
10.1007/BF02646968
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The mechanisms that govern microstructure evolution during reactive plasma spraying of MoSi2 using 100 % methane were investigated, with particular emphasis on the thermodynamics and kinetics of the relevant phase transformations and chemical reactions. The reactive plasma-sprayed MoSi2 exhibited a dense, multilayered microstructure. In addition to the MoSi2 matrix, significant amounts of Mo5Si3 and elemental carbon were observed, along with a small amount of SiC. Thermodynamic and kinetic analysis predicted a large volume fraction of Mo5Si3 and a small amount of SiC in the as-deposited reactive plasma-sprayed MoSi2, in agreement with the experimental observations.
引用
收藏
页码:252 / 260
页数:9
相关论文
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