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MOLECULAR QUANTUM BEAT SPECTROSCOPY

被引：48
作者：
BITTO, H
HUBER, JR
机构：
[1] Physikalisch-Chemisches Institut der Universität Zürich, CH-8057 Zürich
来源：
OPTICS COMMUNICATIONS | 1990年 / 80卷 / 02期
关键词：
D O I：
10.1016/0030-4018(90)90382-4
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
The present account of high-resolution molecular quantum beat spectroscopy emphasizes the versatility of this powerful Doppler-free method. Illustrations are drawn from work on the six-atomic molecule propynal carried out in the authors' laboratory. Examples of anisotropic Zeeman, Stark and hyperfine quantum beats, of isotropic molecular quantum beats and of multi-level quantum beats are discussed with regard to intramolecular relaxation dynamics and the determination of structural parameters such as nuclear hyperfine constants, electric dipole moments, spin-orbit matrix elements and asymmetry-splittings.
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页码：184 / 198
页数：15
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