RETENTION BEHAVIOR OF THE INCLUSION COMPLEXES OF SOME POLYCYCLIC AROMATIC-HYDROCARBONS WITH BETA-CYCLODEXTRIN

被引：13

作者：

LAMPARCZYK, H ^{[1
]}

ZARZYCKI, P ^{[1
]}

OCHOCKA, RJ ^{[1
]}

ASZTEMBORSKA, M ^{[1
]}

SYBILSKA, D ^{[1
]}

机构：

[1] POLISH ACAD SCI,INST PHYS CHEM,PL-01224 WARSAW,POLAND

来源：

CHROMATOGRAPHIA | 1991年 / 31卷 / 3-4期

关键词：

COLUMN LIQUID CHROMATOGRAPHY; CYCLODEXTRIN INCLUSION COMPLEXES; STRUCTURE-RETENTION RELATIONSHIPS; POLYCYCLIC AROMATICS;

D O I：

10.1007/BF02274565

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The retention behaviour of a group of polycyclic aromatic hydrocarbons having nearly equal ionization potentials but different molecular polarizability values was investigated by reversed-phase HPLC and gas chromatography, using beta-cyclodextrin as a selective inclusion reagent. In HPLC, the cyclodextrin was applied as an additive to the ethanol-water binary mobile phase, while in gas chromatography beta-cyclodextrin served as the stationary phase coated on an inert support. The relationships between the capacity factors, molecular polarizabilities and the shape parameter of solute molecules is discussed.

引用

页码：157 / 162

页数：6

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