THE DYNAMIC JAHN-TELLER EFFECT IN THE BENZENE CATION - ROTATIONALLY RESOLVED ZEKE PHOTOELECTRON-SPECTRA OF THE NU-6(E2G) MODE

被引：29

作者：

LINDNER, R ^{[1
]}

SEKIYA, H ^{[1
]}

MULLERDETHLEFS, K ^{[1
]}

机构：

[1] KYUSHU UNIV,INST ADV MAT STUDY,FUKUOKA 812,JAPAN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 09期

关键词：

D O I：

10.1002/anie.199313641

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A textbook example of the dynamic Jahn–Teller effect is provided by the Jahn‐Teller components of the v6 mode of the benzene cation. They were resolved to the rotational level for the first time by zero kinetic energy (ZEKE) photoelectron spectroscopy. The picture on the right shows the ZEKE spec‐trum of the 61(j= ± 1/2) band of the electronic ground state of the benzene cation via the intermediate state S1 61(J′ =1, K′ =1, +l). (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1364 / 1366

页数：3

共 27 条

[1] BERSUKER IB, 1984, JAHNTELLER EFFECT VI
[2] PERTURBATION OF THE JAHN-TELLER EFFECT BY PARTIAL ISOTOPIC-SUBSTITUTION - MULTIMODE VIBRONIC COUPLING IN THE (X)TILDE 2E1G AND (B)TILDE 2E2G STATES OF 1,4-C6H4D2+
EIDING, J
DOMCKE, W
[J]. CHEMICAL PHYSICS, 1992, 163 (01) : 133 - 147
[3] EIDING J, 1992, CHEM PHYS LETT, V177, P345
[4] HIGH-RESOLUTION ZERO KINETIC-ENERGY ELECTRON-SPECTROSCOPY OF AMMONIA
HABENICHT, W
REISER, G
MULLERDETHLEFS, K
[J]. JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (07) : 4809 - 4820
[5] Herzberg G., 1966, MOL SPECTRA MOL STRU, VIII
[6] ELECTRON-SPIN-RESONANCE EVIDENCE FOR THE STATIC DISTORTION OF 2E1G BENZENE CATIONS GIVING 2B2G WITH D2H SYMMETRY IN LOW-TEMPERATURE MATRICES
IWASAKI, M
TORIYAMA, K
NUNOME, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (06) : 320 - 322
[7] Stability of polyatomic molecules in degenerate electronic states. I. Orbital degeneracy
Jahn, HA
Teller, E
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1937, 161 (A905) : 220 - 235
[8] MASS-ANALYZED THRESHOLD IONIZATION (MATI) SPECTROSCOPY IN A CONVENTIONAL TIME-OF-FLIGHT MASS-SPECTROMETER
JOUVET, C
DEDONDERLARDEUX, C
MARTRENCHARDBARRA, S
SOLGADI, D
[J]. CHEMICAL PHYSICS LETTERS, 1992, 198 (3-4) : 419 - 423
[9] DISSOCIATION OF STATE-SELECTED COMPLEX-IONS STUDIED BY MASS-SELECTIVE PULSED FIELD THRESHOLD IONIZATION SPECTROSCOPY
KRAUSE, H
NEUSSER, HJ
[J]. JOURNAL OF CHEMICAL PHYSICS, 1992, 97 (08) : 5923 - 5926
[10] STRUCTURE AND SYMMETRY OF THE BENZENE CATION
LINDNER, R
SEKIYA, H
BEYL, B
MULLERDETHLEFS, K
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (04): : 603 - 606

← 1 2 3 →