STOICHIOMETRICALLY SENSITIZED DECARBOXYLATION OCCURRING IN A MOLECULAR-CRYSTAL COMPOSED OF PHENANTHRIDINE AND 3-INDOLEACETIC ACID

被引:20
作者
KOSHIMA, H [1 ]
DING, KL [1 ]
MATSUURA, T [1 ]
机构
[1] RYUKOKU UNIV,FAC SCI & TECHNOL,DEPT CHEM MAT,OTSU,SHIGA 52021,JAPAN
关键词
D O I
10.1039/c39940002053
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
irradiation of a molecular crystal between phenanthridine and 3-indoleacetic acid at -70 degrees C causes decarboxylation to give 3-methylindole in high yield as the sole product; phenanthridine:behaves like a stoichiometric sensitizer in the crystal.
引用
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页码:2053 / 2054
页数:2
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