STUDIES ON ORGANOPHOSPHORUS COMPOUNDS .48. STRUCTURAL EFFECT ON THE INDUCED ASYMMETRIC ADDITION OF DIALKYL PHOSPHITE TO CHIRAL ALDIMINE DERIVATIVES

被引：42

作者：

YUAN, CY

CUI, SH

机构：

[1] Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1991年 / 55卷 / 1-4期

基金：

中国国家自然科学基金;

关键词：

INDUCED ASYMMETRIC ADDITION; STRUCTURAL EFFECTS; DIALKYL PHOSPHITE ADDITION;

D O I：

10.1080/10426509108045935

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

For the evaluation of the predominating factors controlling the stereochemical process of the addition of dialkylphosphite to a chiral Schiffs base resulting from condensation of substituted benzaldehyde and 1-phenylethylamine, various structural effect of the substrates and phosphorus reagents were investigated. The influence of catalyst and solvent is discussed on the basis of the conformational requirements of the complex formed. © 1991, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：159 / 164

页数：6

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