CONTROLLED RADICAL POLYMERIZATION

被引：68

作者：

GAYNOR, S

GRESZTA, D

MARDARE, D

TEODORESCU, M

MATYJASZEWSKI, K

机构：

[1] Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania, 15213

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY | 1994年 / A31卷 / 11期

关键词：

D O I：

10.1080/10601329408545868

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Various methods which lead to the control of molecular weight and polydispersities, and which allow for the preparation of block copolymers by radical polymerization are discussed. Thermal polymerization of styrenes in the presence of stable radicals, polymerization of vinyl acetate and methyl methacrylate in the presence of chromium complexed by macrocyclic ligands polymerization of vinyl acetate initiated by organoaluminum compounds complexed by dipyridyl and activated by stable radicals, as well as in the presence of phosphites, are described in detail.

引用

页码：1561 / 1578

页数：18

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