EFFICIENT CONVERSION OF THIOGLYCOSIDES INTO GLYCOSYL FLUORIDES USING DIMETHYL(METHYLTHIO)SULFONIUM TETRAFLUOROBORATE

被引：20

作者：

BLOMBERG, L ^{[1
]}

NORBERG, T ^{[1
]}

机构：

[1] BIOCARB TECHNOL AB, DEPT ORGAN SYNTH, S-22370 LUND, SWEDEN

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 1992年 / 11卷 / 06期

关键词：

D O I：

10.1080/07328309208020090

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Alkyl and aryl thioglycosides were converted in high yield into the corresponding alpha-glycosyl fluorides by treatment with dimethyl(methylthio)sulfonium tetrafluoroborate. Glycosidic linkages and most protective groups are not affected by the reaction conditions. Glycosyl fluorides are proposed to be intermediates in glycosylations promoted by dimethyl(methylthio)sulfonium tetrafluoroborate.

引用

页码：751 / 760

页数：10

共 43 条

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