SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A MONOCAPPED-PRISMANE COBALT CLUSTER [CO7(MU-4-S)3(MU-3-S)3(PPH3)4BR1.5CL1.5]

被引：15

作者：

JIANG, FL ^{[1
]}

HUANG, LG ^{[1
]}

LEI, XJ ^{[1
]}

LIU, HQ ^{[1
]}

KANG, BS ^{[1
]}

HUANG, ZY ^{[1
]}

HONG, MC ^{[1
]}

机构：

[1] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,FUJIAN 350002,PEOPLES R CHINA

来源：

POLYHEDRON | 1992年 / 11卷 / 03期

关键词：

D O I：

10.1016/S0277-5387(00)83182-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound has been obtained by treating CoCl(PPh3)3 with excess Li2S in chloroform. An X-ray diffraction study established that the structure of the Co7S6 core can be viewed as a monocapped-prismane or a perfect cube [Co8S6] missing a corner cobalt, missing a corner cobalt, which possesses a crystallographic C3 axis coincident with the Co(1)-P bond.

引用

页码：361 / 363

页数：3

共 11 条

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