EXTRACTION OF BITUMINOUS MATERIAL FROM FOSSIL ORGANIC-MATTER USING LIQUID CARBON-DIOXIDE UNDER LIQUID-VAPOR-EQUILIBRIUM CONDITIONS

被引:5
作者
MARTIN, F
VERDEJO, T
GONZALEZVILA, FJ
机构
[1] Instituto de Recursos Naturales y Agrobiologia, C.S.I.C., 41080 Seville
来源
JOURNAL OF CHROMATOGRAPHY | 1992年 / 607卷 / 02期
关键词
D O I
10.1016/0021-9673(92)87097-R
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Extracts from a peat, a low-rank coal and a bituminous oil shale obtained with liquid carbon dioxide were studied by capillary gas chromatography-mass spectrometry and compared with those obtained by Soxhlet extraction with n-hexane. Although the extraction yields with liquid carbon dioxide were lower, the composition of the extracts, comprising mainly a large variety of linear and cyclic hydrocarbons, was similar in both cases. Owing to the advantages of the liquid carbon dioxide extraction regarding speed, cleanliness and mildness of the extraction conditions, it seems to be an adequate procedure, coupled with gas chromatography-mass spectrometry, to study the biomarker composition of sedimentary organic matter.
引用
收藏
页码:377 / 379
页数:3
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