BORON OXYFLUORIDE GLASSES IN THE B-O-F SYSTEM - NEW POLYMERIC SPAGHETTI-TYPE GLASSES

被引：13

作者：

BOUSSARDPLEDEL, C ^{[1
]}

FONTENEAU, G ^{[1
]}

LUCAS, J ^{[1
]}

机构：

[1] LAB VERRES & CERAM,CNRS,URA 1496,F-35042 RENNES,FRANCE

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1995年 / 188卷 / 1-2期

关键词：

D O I：

10.1016/0022-3093(95)00183-2

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Direct reaction at T = 200 degrees C of gaseous BF3 on B2O3 in a closed silica tube leads to B-O-F glass formation in the cold part of the vessel. The vitreous material obtained from vapour phase condensation has a weak dimensionality as indicated by the low glass transition temperature, T-g = 60 degrees C. The relationship between the trimeric molecular form, B3O3F3, and the polymer glass (BOF)(n) is discussed with respect to formation conditions and glass decomposition.

引用

页码：147 / 152

页数：6

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[2]

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[4]

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