MECHANISM OF THE PHOTOREVERSIBLE CLRE(CO)3(4-PHENYLPYRIDINE)2-INDUCED REDUCTION OF A CU(II) MACROCYCLE

被引：6

作者：

FELIZ, M ^{[1
]}

FERRAUDI, G ^{[1
]}

机构：

[1] UNIV NOTRE DAME,RADIAT LAB,NOTRE DAME,IN 46556

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 181卷 / 2-3期

关键词：

D O I：

10.1016/0009-2614(91)90355-D

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A photoreversible reduction of Cu(II) (TIM)2+ in 350 nm irradiations of ClRe(CO)3(4-phenylpyridine)2 has been investigated by continuous and flash photolyses. The redox reaction involves a metastable Re complex that is photogenerated in parallel with the lowest lying MLCT. The products of the photoredox reaction undergo back electron transfer in the microsecond-millisecond time domain.

引用

页码：201 / 205

页数：5

共 14 条

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