ACCURATE DETERMINATION OF THE EXTENT TO WHICH AN SE2' REACTION OF AN ALLYLSILANE IS ANTI

被引:38
作者
BUCKLE, MJC [1 ]
FLEMING, I [1 ]
GIL, S [1 ]
机构
[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND
关键词
D O I
10.1016/S0040-4039(00)60115-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The E and Z allylsilanes E-1 and Z-1 have been prepared essentially 100% geometrically and enantiomerically pure; their S(E)2' reactions with adamantyl chloride are highly, but not completely, stereospecific.
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页码:4479 / 4482
页数:4
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