CHEMOSELECTIVE METHYLTRIOXORHENIUM(VII)-CATALYZED SULFOXIDATIONS WITH HYDROGEN-PEROXIDE

被引：80

作者：

ADAM, W

MITCHELL, CM

SAHAMOLLER, CR

机构：

[1] Institute of Organic Chemistry, University of Würzburg, D-97074 Würzburg, Am Hubland

来源：

TETRAHEDRON | 1994年 / 50卷 / 46期

关键词：

D O I：

10.1016/S0040-4020(01)89321-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The selective oxidation of sulfides to sulfoxides by hydrogen peroxide under methyltrioxorhenium(VII) catlysis was examined; a high selectivity of sulfoxide over sulfone was achieved, except in the presence of water, which enhanced sulfone formation.

引用

页码：13121 / 13124

页数：4

共 47 条

[1] ABUOMAR MM, 1994, 9TH P INT S HOM CAT
[2] ADAM W, UNPUB J ORG CHEM
[3] ADAM W, UNPUB ANGEW CHEM
[4] ADAM W, UNPUB J MOL CAT
[5] BALICKI R, 1992, LIEBIGS ANN CHEM, P883
[6] OXIDATION OF SULFIDES BY IODYLARENES IN THE PRESENCE OF VANADYL ACETYLACETONATE AS A CATALYST
BARRET, R
PAUTET, F
BORDAT, P
TINLAND, B
DAUDON, M
[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1989, 45 (1-2): : 31 - 33
[7] SURFACE ORGANOMETALLIC CHEMISTRY OF RHENIUM - ATTEMPTS TO CHARACTERIZE A SURFACE CARBENE IN METATHESIS OF OLEFINS WITH THE CATALYST CH3REO3/NB2O5
BUFFON, R
CHOPLIN, A
LECONTE, M
BASSET, JM
TOUROUDE, R
HERRMANN, WA
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1992, 72 (02): : L7 - L10
[8] VANADIUM-PILLARED MONTMORILLONITE CATALYST FOR SELECTIVE OXIDATION OF SULFIDES TO SULFOXIDES
CHOUDARY, BM
RANI, SS
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1992, 75 (01): : L7 - L12
[9] PHOTOOXIDATIONS OF SULFENIC ACID-DERIVATIVES .2. A REMARKABLE SOLVENT EFFECT ON THE REACTIONS OF SINGLET OXYGEN WITH DISULFIDES
CLENNAN, EL
WANG, DY
ZHANG, HW
CLIFTON, CH
[J]. TETRAHEDRON LETTERS, 1994, 35 (27) : 4723 - 4726
[10] HORSERADISH-PEROXIDASE CATALYZED SULFOXIDATION IS ENANTIOSELECTIVE
COLONNA, S
GAGGERO, N
CARREA, G
PASTA, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (04) : 357 - 358

← 1 2 3 4 5 →