SILYL-SUBSTITUTED CARBENES

被引：17

作者：

CREARY, X

WANG, YX

机构：

[1] Department of Chemistry and Biochemistry, University of Notre Dame, Indiana 46556, Notre Dame

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 07期

关键词：

D O I：

10.1021/jo00086a006

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Generation of endo-6-(trimethylsilyl)bicyclo[2.2.1] hept-2-yl carbene and syn-6-(trimethylsilyl)bicycle[2.2.2]oct-2-yl carbene leads to preferential 1,3-migration of the trimethylsilyl group to the carbenic center, while anti-6-(trimethylsilyl)bicycle[2.2.2]oct-2-yl carbene gives preferential migration of the trimethylsilyl-activated hydrogen atom.

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页码：1604 / 1605

页数：2

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