SOLUBILITY OF HYDROGEN IN TITANIUM-ALLOYS .1. THE SOLUBILITY OF HYDROGEN IN THE SYSTEM TI1-XGAX, 0-LESS-THAN-OR-EQUAL-TO-X-LESS-THAN-OR-EQUAL-TO-025

被引:26
作者
MROWIETZ, M
WEISS, A
机构
[1] Technische Hochschule Darmstadt,, Inst fuer Physikalische Chemie III,, Darmstadt, West Ger, Technische Hochschule Darmstadt, Inst fuer Physikalische Chemie III, Darmstadt, West Ger
来源
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1985年 / 89卷 / 01期
关键词
THERMODYNAMICS - TITANIUM AND ALLOYS;
D O I
10.1002/bbpc.19850890111
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Applying the manometric method, the solubility of hydrogen in alloys Ti//1// minus //xGa//x was studied in the range 0 less than equivalent to x less than equivalent to 0. 25; 5 multiplied by (times) 10** minus **5 less than equivalent to p//H//(//2//)/bar less than equivalent to 1; 773 less than equivalent to T/K less than equivalent to 1298. Within the given range of p and T the phase diagram of Ti//1// minus //xGa//xH//r was investigated for 9 compositions x. In the range of solid solutions, 0 less than equivalent to x less than equivalent to 0. 11, with increasing x the range DELTA r of the hcp phase alpha -Ti//1// minus //xGa//xH//r increases slightly, whereas the range of the bcc phase beta -Ti//1// minus //xGa//xH//r narrows strongly with increasing x. The width DELTA r of the two phase region alpha plus beta is nearly independent of x and the phase boundary between beta -phase and ( beta plus gamma ) region shifts with decreasing DELTA r of the beta -phase to smaller r.
引用
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页码:49 / 62
页数:14
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