GAS-CHROMATOGRAPHIC SEPARATION OF THE ENANTIOMERS OF ORGANIC MARINE POLLUTANTS .2. ENANTIOSELECTIVE METABOLISM OF (+/-)-ALPHA-1,2,3,4,5,6-HEXACHLOROCYCLOHEXANE IN ORGANS OF THE EIDER DUCK

被引：40

作者：

KALLENBORN, R ^{[1
]}

HUHNERFUSS, H ^{[1
]}

KONIG, WA ^{[1
]}

机构：

[1] UNIV HAMBURG,INST ORGAN CHEM,MARTIN LUTHER KING PL 6,W-2000 HAMBURG 13,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 03期

关键词：

D O I：

10.1002/anie.199103201

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Also enantiomers of synthetic pollutants can be "recognized" in enzymatic degradation reactions. This is demonstrated by the enantioselective metabolization of technical alpha-HCH, a highly chlorinated, chiral hydrocarbon, in the liver of cider ducks. Extracts of this organism contain almost exclusively (+)-z-HCH, i.e. the (-)-isomer is degraded much more rapidly.

引用

页码：320 / 321

页数：2