UTILITY OF PHOSPHONIUM-SUBSTITUTED ESTER ENOLATES AS SYNTHETIC INTERMEDIATES - A NOVEL TRIALKYLPHOSPHINE-CATALYZED [3,3] REARRANGEMENT OF ALLYLIC ACRYLATES

被引：19

作者：

HANAMOTO, T ^{[1
]}

BABA, Y ^{[1
]}

INANAGA, J ^{[1
]}

机构：

[1] INST MOLEC SCI,OKAZAKI,AICHI 444,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 02期

关键词：

D O I：

10.1021/jo00054a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel Ireland-type [3,3] rearrangement which utilizes a catalytic amount of a trialkylphosphine with allylic acrylates has been developed as a synthetic entry into alpha-methylene-gamma,delta-unsaturated carboxylic acids.

引用

页码：299 / 300

页数：2

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