REACTIONS OF DIBORON TETRAHALIDES WITH SOME UNSATURATED ORGANOMETALLIC COMPOUNDS

被引：17

作者：

COYLE, TD

RITTER, JJ

机构：

[1] Inorganic Chemistry Section, National Bureau of Standards, Washington

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1968年 / 12卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)93848-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetrachloro- and tetrafluorodiborane(4) add to the double bond in a number of vinyl derivatives of boron, carbon, silicon, germanium, and tin to form 1,2-bis(dihaloboryl)ethyl derivatives. Most of the compounds are stable in vacuo at temperatures in excess of 150°. Tetrachlorodiborane(4) undergoes addition considerably more readily than does tetrafluorodiborane(4). Relative rates of addition have been determined and shown to be markedly dependent on the nature of the substituent on the vinyl group. © 1968.

引用

页码：269 / &

共 33 条

[1] HYDRIDE-TRANSFER REACTIONS OF BORINE .1. SYNTHESIS OF BORON CARBON BONDS FROM THE FLUOROETHYLENES
BARTOCHA, B
GRAHAM, WAG
STONE, FGA
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1958, 6 (02): : 119 - 129
[2] BINGER P, 1961, TETRAHEDRON LETT, P156
[3] BIRCHALL JM, 1961, CHEM IND-LONDON, P1080
[4] ORGANOBORON HALIDES .2. THE VINYLHALOBORANES, A PRELIMINARY STUDY OF THEIR PREPARATION AND PROPERTIES
BRINCKMAN, FE
STONE, FGA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (24) : 6218 - 6223
[5] BRINCKMAN FE, 1965, 150 M AM CHEM SOC AT, pO41
[6] DIBORON TETRACHLORIDE AND TETRAFLUORIDE AS REAGENTS FOR THE SYNTHESIS OF ORGANO-BORON COMPOUNDS .2. THE BEHAVIOR OF THE DIBORON TETRAHALIDES TOWARD UNSATURATED ORGANIC COMPOUNDS
CERON, P
FINCH, A
FREY, J
KERRIGAN, J
PARSONS, T
URRY, G
SCHLESINGER, HI
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (24) : 6368 - 6371
[7] CHAMBERS C, 1964, P CHEM SOC LONDON, P286
[8] CHEMICAL AND SPECTROSCOPIC EVIDENCE FOR OCCURRENCE OF PI-CHARACTER IN CARBON-BORON BONDS
COYLE, TD
STONE, FGA
STAFFORD, SL
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1961, (JUL): : 3103 - &
[9] ORGANOBORON HALIDES .3. LEWIS ACIDITY AND F-19 NUCLEAR MAGNETIC RESONANCE SPECTRA OF SOME ORGANODIFLUOROBORANES
COYLE, TD
STONE, FGA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (24) : 6223 - 6228
[10] MOLECULAR ADDITION COMPOUNDS OF BORON .5. PROTON CHEMICAL SHIFTS AND STABILITY OF ADDUCTS
COYLE, TD
STONE, FGA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (20) : 4138 - &

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