SYNTHESES OF ALL-TRANS ACYCLIC ISOPRENOID PHEROMONE COMPONENTS

被引：8

作者：

BAECKSTROM, P

LI, L

机构：

[1] Department of Organic Chemistry, Royal Institute of Technology

来源：

TETRAHEDRON | 1991年 / 47卷 / 32期

关键词：

D O I：

10.1016/S0040-4020(01)86580-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

All-trans acyclic isoprenoid skeletons were made through a two-step iterative sequence. The method involves the Claisen rearrangement of allyl vinyl ethers formed from allylic alcohols and the dimethyl acetal of methyl isopropenyl ketone, followed by LiAlH4 reduction of the alpha,beta-unsaturated ketone formed by rearrangement. The alpha,beta-unsaturated ketone was also transformed to the 2-methyl-1-propenyl group by using a one-pot deoxygenation reaction for the synthesis of (E)-beta-farnesene, (E)-beta-springene and dendrolasin.

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页码：6533 / 6538

页数：6

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