SYNTHESIS OF NEW POLYMERS CONTAINING ALPHA-(TRIFLUOROMETHYL)ACRYLATE UNITS

被引：32

作者：

AGLIETTO, M

PASSAGLIA, E

DIMIRABELLO, LM

BOTTEGHI, C

PAGANELLI, S

MATTEOLI, U

MENCHI, G

机构：

[1] UNIV VENICE,DIPARTIMENTO CHIM,I-30100 VENICE,ITALY

[2] UNIV FLORENCE,DIPARTIMENTO CHIM ORGAN,I-50121 FLORENCE,ITALY

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1995年 / 196卷 / 09期

关键词：

D O I：

10.1002/macp.1995.021960910

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Free radical polymerization of both alpha-(trifluoromethyl)acrylic acid (TFMAA) and its methyl ester MTFMA is shown to be possible in the presence of bis(4-tert-butylcyclohexyl) peroxycarbonate (Percadox) as initiator and dioxane or THF as solvent. Also it is shown that copolymers of TFMAA with alpha-olefins (1-decene, 2-methyl-1-hexene) and of methyl alpha-(trifluoromethyl)acrylate (MTFMA) with vinyl ethers (butyl, 2-ethylhexyl, and menthyl vinyl ether) can be simply obtained with AIBN as initiator; these copolymers have a predominantly alternating structure.

引用

页码：2843 / 2853

页数：11

共 10 条

[1] STUDIES UPON ALPHA-TRIFLUOROMETHYLACRYLIC ACID, ALPHA-TRIFLUOROMETHYLPROPIONIC ACID, AND SOME DERIVED COMPOUNDS [J].