THE SYNTHESIS OF SUBSTITUTED LACTONES BY INTRAMOLECULAR CHIRALITY TRANSFER WITH STEREODIFFERENTIATING CHIRAL ALPHA-ESTER RADICAL INTERMEDIATES

被引：63

作者：

HANESSIAN, S

DIFABIO, R

MARCOUX, JF

PRUDHOMME, M

机构：

[1] Department of Chemistry, Universite de Montreal, Montreal, QC,H3C 3J7, Box 6128, Station A

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 11期

关键词：

D O I：

10.1021/jo00298a005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

: Carbon radicals generated from a-halo acetate, propionate, and related allylic and homoallylic esters can cyclize onto activated and unactivated olefins to give α,-β-substituted lactones with good to excellent stereochemical control in yields ranging from 52 to 90%. © 1990, American Chemical Society. All rights reserved.

引用

页码：3436 / 3438

页数：3

共 30 条

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