ON THE SORPTION OF GASES AND LIQUIDS IN GLASSY-POLYMERS

被引：68

作者：

LEIBLER, L

SEKIMOTO, K

机构：

[1] Groupe de Physico-Chimie Théorique, ESPCI, F75231 Paris Cedex 05

来源：

MACROMOLECULES | 1993年 / 26卷 / 25期

关键词：

D O I：

10.1021/ma00077a034

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We present a thermodynamic theory of solubility of gases, vapors, and low-molecular-weight liquids in glassy polymers. We show that the distinctive features of sorption in glassy systems may be simply related to their elastic properties. As an illustration we analyze the data of vinyl chloride monomer absorption in poly(vinyl chloride) at various temperatures and vapor pressures and find a quantitative agreement with the model without any adjustable parameters.

引用

页码：6937 / 6939

页数：3

共 15 条

[1] GAS SORPTION IN POLYMERS BASED ON BISPHENOL-A [J].