N-15 NMR OF STERICALLY DISTORTED CYANOMET HEMES

被引：7

作者：

AVILES, G ^{[1
]}

CHANG, CK ^{[1
]}

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 01期

关键词：

D O I：

10.1039/c39920000031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sterically distorted Fe-CN bonds created by 'strapped' iron(III) porphyrins exhibit a large upfield shift in the cyanide N-15 NMR signal, making the steric effect on the distal side an important consideration in interpreting the N-15 NMR spectra of cyanomet haemoproteins.

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页码：31 / 32

页数：2

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