THE REACTIVITY TOWARDS THE BENZOYLOXY RADICAL OF 1,4-BIS(2-METHYLSTYRYL) BENZENE

被引：1

作者：

BARSON, CA

BEVINGTON, JC

HUCKERBY, TN

机构：

[1] UNIV LANCASTER,CTR POLYMER,LANCASTER LA1 4YA,ENGLAND

[2] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND

来源：

POLYMER | 1991年 / 32卷 / 18期

关键词：

1,4-BIS(2-METHYLSTYRYL)BENZENE; METHYL METHACRYLATE; BENZOYL PEROXIDE; RADICAL POLYMERIZATION; END GROUPS;

D O I：

10.1016/0032-3861(91)90546-U

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

It has been found that 1,4-bis(2-methylstyryl)benzene (MSB) is approximately 520 times as effective as methyl methacrylate in capturing the benzoyloxy radicals generated at 60-degrees-C by dissociation of benzoyl peroxide. This result has been obtained from examinations of the end groups in samples of poly (methyl methacrylate) prepared using benzoyl peroxide as initiator in the presence of MSB at low concentrations.

引用

页码：3415 / 3417

页数：3

共 7 条

[1] STUDIES OF END-GROUPS IN POLY(METHYL METHACRYLATE) PREPARED USING BENZOYL PEROXIDE IN THE PRESENCE OF DIPHENYLPROPENES [J].