AQUEOUS ORGANOMETALLIC CHEMISTRY - SYNTHESIS AND STRUCTURE OF CHLORO[(1-3-ETA-6-8-ETA)-2,7-DIMETHYLOCTADIENEDIYL](SEMICARBAZIDE)-RUTHENIUM(IV) CHLORIDE DIHYDRATE

被引：27

作者：

SOMMERER, SO ^{[1
]}

PALENIK, GJ ^{[1
]}

机构：

[1] UNIV FLORIDA,CTR MOLEC STRUCT,DEPT CHEM,GAINESVILLE,FL 32611

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 05期

关键词：

D O I：

10.1021/om00051a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first example of a water-soluble cationic Ru(IV) complex with two eta-3-allyl functions has been isolated and characterized by an X-ray crystal structure study. The Ru ion is at the center of a distorted trigonal bipyramid where the equatorial donors are two eta-3-allyl functions and a terminal semicarbazide N. The O of the semicarbazide and Cl reside in the axial positions.

引用

页码：1223 / 1224

页数：2

共 17 条

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