AN INTRAMOLECULAR W-H-O=C HYDROGEN-BOND - ELECTROSYNTHESIS AND X-RAY CRYSTALLOGRAPHIC STRUCTURE OF [WH3(ETA(1)-OCOME)(PH(2)PCH(2)CH(2)PPH(2))(2)]

被引：30

作者：

FAIRHURST, SA ^{[1
]}

HENDERSON, RA ^{[1
]}

HUGHES, DL ^{[1
]}

IBRAHIM, SK ^{[1
]}

PICKETT, CJ ^{[1
]}

机构：

[1] UNIV SUSSEX,NITROGEN FIXAT LAB,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 15期

关键词：

D O I：

10.1039/c39950001569

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical reduction of [WH2(eta(2)-OCOMe)(dppe)(2)](+) in the presence of protons leads to the formation of [WH3(eta(1)-OCOMe)(dppe)(2)]: NMR and X-ray crystallographic data suggest this complex possesses an unprecedented W-H...O=C intramolecular hydrogen-bond.

引用

页码：1569 / 1570

页数：2

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