CHEMISTRY OF [NET4][10-ENDO-(AU(PPH3))-7,8-NIDO-C2B9H9ME2] - CARBORANE CAGE TRANSFER FROM GOLD TO RHODIUM AND IRIDIUM

被引：18

作者：

HOWARD, JAK ^{[1
]}

JEFFERY, JC ^{[1
]}

JELLISS, PA ^{[1
]}

SOMMERFELD, T ^{[1
]}

STONE, FGA ^{[1
]}

机构：

[1] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 23期

关键词：

D O I：

10.1039/c39910001664

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The salt [NEt4][10-endo-{Au(PPh3)}-7,8-nido-C2B9H9Me2] has been used to synthesise several complexes in which gold forms bonds with rhodium and iridium, including [IrAuH(mu-sigma,eta-3-C2B9H8Me2)(PPh3)3], [exo-nido-5,10-{Rh(PPh3)2}-5,10-mu-(H)2-10-endo-{Au(PPh3)}-7,8-C2B9H7Me2].CH2Cl2, and [RhAu2(mu-H)(PPh3)3(eta-5-C2B9H9Me2)].2(CH2Cl2).

引用

页码：1664 / 1666

页数：3

共 9 条

[1]

[Anonymous], 1974, INT TABLES XRAY CRYS, VIV

[2] THE STRUCTURE OF [7,8-C2B9H12]- - CORRECTION OF A POPULAR MISCONCEPTION [J].