STRUCTURE OF DICHLOROBIS(2-CHLOROIMIDAZOLE)DIMETHYLTIN(IV)

被引：12

作者：

CASELLATO, U

GRAZIANI, R

GONZALEZ, AS

机构：

[1] UNIV PADUA,DIPARTIMENTO CHIM INORGAN,PADUA,ITALY

[2] UNIV SANTIAGO DE COMPOSTELA,DEPT QUIM INORGAN,SANTIAGO,SPAIN

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1992年 / 48卷

关键词：

D O I：

10.1107/S0108270192003822

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[SnCl2(CH3)2(C3H3ClN2)2], monoclinic, P2(1)/a, a = 7.408 (3), b = 14.318 (5), c = 7.188 (3) angstrom, beta = 112.59(4)-degrees, V = 703.9(5) angstrom3, Z = 2, D(x) = 2.003 Mg m-3, lambda(Mo Kalpha) = 0.7107 angstrom, mu = 2.572 mm-1, F(000) = 412, R = 0.037 for 1488 reflections with I > 3sigma(I). The title compound crystallizes as centrosymmetric trans octahedral (OC-6-12)-[SnMe2Cl2(C3H3ClN2)2] molecules. The crystal packing is stabilized by a complex network of intermolecular hydrogen bonds between the coordinated Cl atoms and the N-H groups of the organic ligands of the neighbouring units.

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页码：2125 / 2126

页数：2

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