NEW, CHIRAL SILYLATED ORGANOPHOSPHORUS(III) REAGENTS - SYNTHESES AND APPLICATIONS IN THE ASYMMETRIC PHOSPHORYLATION OF ALDEHYDES

被引：29

作者：

SUM, V ^{[1
]}

DAVIES, AJ ^{[1
]}

KEE, TP ^{[1
]}

机构：

[1] UNIV LEEDS,DEPT CHEM,LEEDS LS2 9JT,W YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 24期

关键词：

D O I：

10.1039/c39920001771

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new silylated organophosphorus(III) compounds, (1R,2S)-(O,N-ephedrine)POSiR3(R3 = Ph3, Bu(t)Me2, Et3) have been synthesised and shown to react with benzaldehyde to afford the phosphonate esters (1R,2S)-(O,N-ephedrine)P(=O)CHPh(OSiR3) with good stereoselectivity.

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页码：1771 / 1773

页数：3

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