ZEROVALENT PALLADIUM AND PLATINUM COMPLEXES OF AMINOMETHYLPHOSPHINES - CRYSTAL-STRUCTURE OF THE PALLADIUM(0) DIBENZYLIDENEACETONE COMPLEX [PD(PHCH=CHCOCH=CHPH)(((C6H11)(2)PCH2)(2)NME)]

被引：38

作者：

FAWCETT, J ^{[1
]}

KEMMITT, RDW ^{[1
]}

RUSSELL, DR ^{[1
]}

SERINDAG, O ^{[1
]}

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,LEICS,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 486卷 / 1-2期

关键词：

PALLADIUM; PLATINUM; AMINOMETHYLPHOSPHINES; DIBENZYLIDENEACETONE; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)05023-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tris(dibenzylideneacetone)dipalladium and bis(dibenzylideneacetone)platinum re act with N, N-bis(dicyclohexylphosphinomethyl)methylamine, (Cy(2)PCH(2))(2)NMe (Cy = cyclohexyl), and with N, N-bis(diphenylphosphinomethyl)methylamine, (Ph(2)PCH(2))(2)NMe (Ph = phenyl), to give the complexes [M(dba){(R(2)PCH(2))(2)NMe}] (M = Pd or Pt, dba = dibenzylideneacetone), R = Cy or Ph. Thezerovalent platinum complex [Pt(PPh(3)){(Cy(2)PCH(2))(2)NMe}] can be obtained by hydrazine hydrate reduction of a mixture of [PtCl2{(Cy(2)PCH(2))(2)NMe}] and triphenylphosphine or one of cis-[PtCl2(PPh(3))(2)] and (Cy(2)PCH(2))(2)NMe. The crystal structure of [Pd(dba){(Cy(2)PCH(2))(2)NMe}] has been determined and some reactions of the complexes are reported.

引用

页码：171 / 176

页数：6

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