IRIDOIDS IN THE FLORA OF ITALY .12. ISOLATION AND PARTIAL SYNTHESIS OF 7,8-DEHYDRO-6-BETA,10-DIHYDROXY-11-NORIRIDOMYRMECIN, A METHYLCYCLOPENTANOID MONOTERPENE FROM SCROPHULARIA-CANINA

被引：18

作者：

BERDINI, R ^{[1
]}

BIANCO, A ^{[1
]}

GUISO, M ^{[1
]}

MARINI, E ^{[1
]}

NICOLETTI, M ^{[1
]}

PASSACANTILLI, P ^{[1
]}

RIGHI, G ^{[1
]}

机构：

[1] UNIV ROMA LA SAPIENZA,DIPARTMENTO CHIM,I-00185 ROME,ITALY

来源：

JOURNAL OF NATURAL PRODUCTS | 1991年 / 54卷 / 05期

关键词：

D O I：

10.1021/np50077a027

中图分类号：

Q94 [植物学];

学科分类号：

071001 [植物学];

摘要：

A new cyclopentanoid monoterpene lactone 2 was isolated from Scrophularia canina, together with the known iridoid glucosides aucubin [1], harpagide, 8-O-acetylharpagide, and 10-O-beta-glucosylaucubin. The partial synthesis of 2, performed starting from aucubin [1], allowed demonstration of its structure and absolute configuration of 7,8-dehydo-6-beta, 10-dihydroxy-11-noriridomyrmecin.

引用

页码：1400 / 1403

页数：4

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