SYNTHETIC STUDIES TOWARDS COMPLEX DITERPENOIDS .19. TOTAL SYNTHESIS OF (PLUS-OR-MINUS)-DEOXOFAVELINE, (PLUS-OR-MINUS)-FAVELINE METHYL-ETHER AND (PLUS-OR-MINUS)-FAVELINE

被引：17

作者：

GHOSH, AK ^{[1
]}

MUKHOPADHYAY, C ^{[1
]}

GHATAK, UR ^{[1
]}

机构：

[1] INDIAN ASSOC CULTIVAT SCI,DEPT ORGAN CHEM,CALCUTTA 700032,W BENGAL,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 03期

关键词：

D O I：

10.1039/p19940000327

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Simple and efficient syntheses have been developed for the cytotoxic dinorditerpenoids, deoxofaveline 1. (+/-)-faveline methyl ether 2 and (+/-)-faveline 3, having a hexahydrodibenzo[a,d]cycloheptene ring system. through the enolizable tricyclic ketone mixture 12 and 13, prepared from the easily accessible 2-arylethyl-3,3-dimethylcyclohexanone 7.

引用

页码：327 / 332

页数：6

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