INVESTIGATIONS ON A HOMOGENEOUS WILKINSONS CATALYST FOR THE WATER PHOTOLYSIS

被引：19

作者：

BAUER, R

WERNER, HAF

机构：

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 1994年 / 19卷 / 06期

关键词：

D O I：

10.1016/0360-3199(94)90003-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mass spectroscopy experiments proved that hydrogen produced with trisodium chlorotris(diphenylphosphinobenzene-m-sulphonate)rhodium(I) [= Na3Rh(I)Cl(dpm)3] as catalyst originates from water and not from water and not from ascorbic acid. The catalyst showed high activity by the photochemical reduction of water [system: Ru(bipy)3(2+), Rh(I)Cl(dpm)33-, ascorbic acid; lambda > 400 nm] with turn-over number > 2000 in the presence of oxygen.

引用

页码：497 / 499

页数：3

共 14 条

[1] PHOTOCHEMICAL GENERATION OF RU(BPY)3+ AND O2-
ANDERSON, CP
SALMON, DJ
MEYER, TJ
YOUNG, RC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (06) : 1980 - 1982
[2] BAUER R, 1991, Z NATURFORSCH B, V46, P1544
[3] PHOTOCHEMICAL CLEAVAGE OF WATER BY PHOTOCATALYSIS
BORGARELLO, E
KIWI, J
PELIZZETTI, E
VISCA, M
GRATZEL, M
[J]. NATURE, 1981, 289 (5794) : 158 - 160
[4] SUSTAINED WATER CLEAVAGE BY VISIBLE-LIGHT
BORGARELLO, E
KIWI, J
PELIZZETTI, E
VISCA, M
GRATZEL, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (21) : 6324 - 6329
[5] BOROWSKI AF, 1978, NOUV J CHIM, V2, P137
[6] OXYGEN QUENCHING OF CHARGE-TRANSFER EXCITED-STATES OF RUTHENIUM(II)COMPLEXES - EVIDENCE FOR SINGLET OXYGEN PRODUCTION
DEMAS, JN
DIEMENTE, D
HARRIS, EW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (20) : 6864 - 6865
[7] GRATZEL M, 1981, PHOTOCHEMICAL CONVER, P131
[8] LIGHT-INDUCED ELECTRON-TRANSFER REACTIONS INVOLVING THE TRIS(2,2'-BIPYRIDINE)RUTHENIUM DICATION AND RELATED COMPLEXES .1. THE BIS(2,2'-BIPYRIDINE)(DIETHYL2,2'-BIPYRIDINE-4,4'-DICARBOXYLATE)RUTHENIUM DICATION
JOHANSEN, O
LAUNIKONIS, A
MAU, AWH
SASSE, WHF
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1980, 33 (08) : 1643 - 1648
[9] SOLAR REDUCTION OF WATER .1. COMPETITION BETWEEN LIGHT-INDUCED HYDROGEN FORMATION AND HYDROGENATION OF METHYLVIOLOGEN IN THE SYSTEM WATER-TRIS(2,2'-BIPYRIDINE)RUTHENIUM "DICATION-ETHYLENEDIAMINETETRAACETIC ACID-PLATINUM
JOHANSEN, O
LAUNIKONIS, A
LODER, JW
MAU, AWH
SWIFT, JD
WELLS, D
SASSE, WHF
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1981, 34 (05) : 981 - 991
[10] SOLAR REDUCTION OF WATER .3. IMPROVED ELECTRON-TRANSFER AGENTS FOR THE SYSTEM WATER TRIS(2,2'-BIPYRIDINE)RUTHENIUM DICATION ETHYLENEDIAMINETETRAACETIC ACID PLATINUM
LAUNIKONIS, A
LODER, JW
MAU, AWH
SASSE, WHF
SUMMERS, LA
WELLS, D
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1982, 35 (07) : 1341 - 1355

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